A thermocouple is an electrical device that measures temperature using two different electrical conductors that form a junction. The device generates a temperature-dependent voltage through the Seebeck effect, enabling precise temperature measurements across an extensive range
Operating Principles
The Seebeck Effect Powers Temperature Detection
The Seebeck effect creates an electromotive force when temperature differences exist between two points of an electrical conductor. Under open-circuit conditions, the voltage gradient is directly proportional to the temperature gradient, following the equation ∇V=−S(T)∇T∇V=−S(T)∇T, where S(T) represents the Seebeck coefficient
Junction Configuration Enables Measurement
The thermocouple consists of a measuring (hot) junction and a reference (cold) junction. The voltage difference between these junctions provides the temperature reading. The measured voltage follows the equation V=∫TrefTsense(S+(T)−S−(T)) dTV=∫TrefTsense(S+(T)−S−(T))dT
Industrial Applications
Temperature Monitoring in Manufacturing
Thermocouples serve critical roles in industrial processes, measuring temperatures in kilns, gas turbine exhausts, and diesel engines. The devices can measure temperatures from -270°C to +3000°C in specific conditions
Steel Industry Implementation
Type B, Type S, Type R, and Type K thermocouples monitor temperatures throughout steel production. Disposable Type S thermocouples measure molten steel temperature before tapping in electric arc furnaces
Safety Applications
Gas Appliance Protection
Thermocouples act as fail-safe devices in gas-powered appliances. The device monitors pilot flames – if the flame extinguishes, the thermocouple cools, dropping voltage and automatically closing the gas valve to prevent gas leaks
Types and Specifications
Common Varieties
Type K thermocouples (chromel-alumel) serve as general-purpose sensors, offering sensitivity of 41 μV/°C and operating between -200°C to +1350°C. Type J (iron-constantan) provides higher sensitivity at 50 μV/°C but operates in a narrower range (-40°C to +1200°C)
Noble Metal Variants
Platinum/rhodium-alloy thermocouples (Types B, R, and S) deliver high stability but lower sensitivity (approximately 10 μV/°C). These types excel in high-temperature applications despite their higher cost
Practical Considerations
Insulation Requirements
The thermocouple wires require complete insulation from each other, except at the sensing junction. Plastics insulate effectively at low temperatures, while ceramics work up to 1000°C. Vacuum or inert gas insulation suits very high-temperature applications
Aging Effects
High-temperature exposure causes thermocouple aging, affecting measurement accuracy over time. Chemical and metallurgical changes can create inhomogeneities in the conductors, leading to measurement errors. This aging process particularly impacts thermocouples used in furnaces and reactive atmospheres
A thermocouple, also known as a "thermoelectrical thermometer", is an electrical device consisting of two dissimilar electrical conductors forming an electrical junction. A thermocouple produces a temperature-dependent voltage as a result of the Seebeck effect, and this voltage can be interpreted to measure temperature. Thermocouples are widely used as temperature sensors.

Commercial thermocouples are inexpensive, interchangeable, are supplied with standard connectors, and can measure a wide range of temperatures. In contrast to most other methods of temperature measurement, thermocouples are self-powered and require no external form of excitation. The main limitation with thermocouples is accuracy; system errors of less than one degree Celsius (°C) can be difficult to achieve.
Thermocouples are widely used in science and industry. Applications include temperature measurement for kilns, gas turbine exhaust, diesel engines, and other industrial processes. Thermocouples are also used in homes, offices and businesses as the temperature sensors in thermostats, and also as flame sensors in safety devices for gas-powered appliances.